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A new tricyclic triketone from tandem condensation reactions |
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| Authors: | I David Reingold Anna M Butterfield Robert S Walters Jr Susan Scheuring Milan Gembický Peter Baran |
| Institution: | a Department of Chemistry, Juniata College, Huntingdon, PA 16652, USA b Department of Chemistry, SUNY Buffalo, Buffalo, NY 14260-3000, USA |
| Abstract: | Perhydrophenanthrene-1,5,10-trione (6) was isolated from the reaction of methyl 3-(carboxymethyl)cyclohexanone and cyclohexenone in a tandem Michael-Claisen reaction. NMR and X-ray analysis confirmed the structure of the product. |
| Keywords: | Michael Claisen Tricyclic Triketone Modeling Tandem condensations Kekulene Perhydrophenanthrene |
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