o-Bornylphenol: Stereochemistry and synthesis of new derivatives from its (+)-enantiomer |
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| Authors: | E. V. Buravlev I. Yu. Chukicheva O. A. Shumova K. Yu. Suponitskii A. V. Kutchin |
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| Affiliation: | 1. Institute of Chemistry, Komi Research Center, Ural Branch, Russian Academy of Sciences, ul. Pervomaiskaya 48, Syktyvkar, 167982, Russia
2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia
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| Abstract: | New derivatives of the (+)-enantiomer of o-bornylphenol were synthesized with a view to determine the configuration of chiral centers therein. The absolute configuration of the terpene substituents in the Mannich reaction product obtained from 4,13-diaza-18-crown-6 was estimated as (1R,2R,4S) on the basis of anomalous X-ray scattering. |
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