Synthesis of 1,3-dimethyladamantane by skeletal rearrangement of C12H18 and C12H20 hydrocarbons over Na/H-Y-zeolite |
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Authors: | R I Khusnutdinov K S Kislitsina A N Khazipova B I Kutepov |
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Institution: | 1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, Ufa, 450075, Bashkortostan, Russia
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Abstract: | Granular binder-free Y-zeolite with a degree of Na+/H+ ion exchange of 0.97 efficiently catalyzed isomerization of tetracyclo6.2.1.13,6.02,7]dodecane and (2aR,5aα,8aR,8bα)-dodecahydroacenaphthene (perhydroacenaphthene) to 1,3-dimethyladamantane. |
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