Zirconium-catalyzed reaction of terminal alkenes with triethylindium |
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| Authors: | I. R. Ramazanov L. K. Dil’mukhametova U. M. Dzhemilev |
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| Affiliation: | 1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, Ufa, 450075, Bashkortostan, Russia
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| Abstract: | Terminal alkenes (undec-1-ene, oct-1-ene, and allylbenzene) reacted with triethylindium in the presence of a catalytic amount of Cp2ZrCl2 in hexane to give mixtures of three organoindium compounds whose hydrolysis in D2O afforded 2-substituted 1,4-dideuterobutane containing minor amounts of 2-substituted 1- and 4-deuterobutanes. |
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