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Crystal structures of copper(II) and nickel(II) complexes with 1,3-bis(3,5-di-tert-butylsalicylideneamino)propan-2-ol
Authors:L D Popov  S I Levchenkov  I N Shcherbakov  K Yu Suponitskii  Yu P Tupolova  V V Lukov  V A Kogan
Institution:1. Southern Federal University, Rostov-on-Don, Russia
2. Southern Scientific Center, Russian Academy of Sciences, Rostov-on-Don, Russia
3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia
Abstract:Mononuclear copper(II) and nickel(II) complexes with 1,3-bis(3,5-di-tert-butylsalicylideneamino)propan-2-ol (H3L) of the general formula M(HL)] were obtained and structurally characterized. It was demonstrated that the presence of the tert-butyl groups precludes intermolecular hydrogen bonding in the crystals of the complexes and that their molecules are only linked by hydrophobic interactions.
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