Crystal structures of copper(II) and nickel(II) complexes with 1,3-bis(3,5-di-tert-butylsalicylideneamino)propan-2-ol |
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Authors: | L D Popov S I Levchenkov I N Shcherbakov K Yu Suponitskii Yu P Tupolova V V Lukov V A Kogan |
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Institution: | 1. Southern Federal University, Rostov-on-Don, Russia 2. Southern Scientific Center, Russian Academy of Sciences, Rostov-on-Don, Russia 3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia
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Abstract: | Mononuclear copper(II) and nickel(II) complexes with 1,3-bis(3,5-di-tert-butylsalicylideneamino)propan-2-ol (H3L) of the general formula M(HL)] were obtained and structurally characterized. It was demonstrated that the presence of the tert-butyl groups precludes intermolecular hydrogen bonding in the crystals of the complexes and that their molecules are only linked by hydrophobic interactions. |
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