Structure of monolayer silica on Mo(1 1 2) investigated by rainbow scattering under axial surface channeling

The structure of a monolayer crystalline silica film grown on a Mo(1 1 2) substrate is investigated via grazing scattering of fast atoms. For scattering along low indexed directions in the surface plane (“axial surface channeling”) the corrugation of the interaction potential leads to an azimuthal out-of plane scattering with an intensity enhancement for the maximum deflection angle, the so called “rainbow”. From the comparison of the experimental angular distributions for scattered projectiles with classical trajectory simulations we obtain information on the arrangement of atoms in the topmost surface layer. Our work provides evidence for the structural model of a two-dimensional network for the silica film.