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A heatproof separator for lithium-ion battery based on nylon66 nanofibers
Authors:Haolun Wang  Ning Wang  Tao Liu  Chunsong Zhao  Xi Luo  Lifang Zhang  Yulei Chang  Hui Wu
Institution:1.State Key Laboratory of Electronic Thin Films and Integrated Devices,University of Electronic Science and Technology of China,Chengdu,China;2.State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering,Tsinghua University,Beijing,China
Abstract:The safety of lithium-ion battery is closely related to the anti-shrink and heatproof stability of the separator. In this paper, electrospun nylon66 (PA66) nanofiber-based membrane is used as lithium-ion battery separator, showing good thermodynamics properties via thermogravimetric analysis (TG), thermal shrinkage experiment, and tension test. Furthermore, electrospun nylon66 separator based battery exhibits better safety than the battery applying Celgard commerce separator under the condition of high temperature and severe vibration. Meanwhile, the electrochemical properties of both batteries are nearly identical. These facts prove that the electrospun nylon66 separator is an ideal separator candidate for power lithium-ion battery of electric vehicles. In addition, the nylon66 separator annealed in the air has higher tensile strength and better property of elongation than the unannealed one.
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