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| 纳米SnO2的非水溶剂溶胶-凝胶法制备与表征 | |
| 引用本文： | 何则强,熊利芝,麻明友,肖卓炳,吴显明,黄可龙.纳米SnO2的非水溶剂溶胶-凝胶法制备与表征[J].无机化学学报,2005,21(11):1691-1696. |
| 作者姓名： | 何则强 熊利芝 麻明友 肖卓炳 吴显明 黄可龙 |
| 作者单位： | 1. 吉首大学化学化工学院,吉首,416000;中南大学化学化工学院,长沙,410083 2. 吉首大学化学化工学院,吉首,416000 3. 中南大学化学化工学院,长沙,410083 |
| 基金项目： | 国家自然科学基金项目(No.20376086)，湖南省教育厅优秀青年项目(No.04B016)，中南大学博士后科学基金资助项目(No.2004107)资助。 |
| 摘 要： | Nanometer SnO2 powders were successfully prepared by non-hydrolytic sol-gel approach combined with heat treatments using tin tetrachloride as starting material and ethylene glycol as solvent. The reaction mechanism of the sol-gel process is proposed. Results indicate that the -OHCH2CH2OH- prevent Cl- ion from accessing to tin Sn4+ due to steric effect, and hence increaseing the stability of the sol solution. Ethylene glycol functions not only as a complextion agent to form a polymer network but also as a “spacer” to modulate the distance between metal ions, preventing metal oxide particles from aggregation during desiccation of the sol. The effects of heat treatments on the evolution of structure and morphology of nanosized SnO2 powders were studied. The powders with narrow size distribution around 15～20 nm could be obtained at 500 ℃ for 4 h. |
| 关 键 词： | SnO2 纳米材料 溶胶凝胶法 |
| 文章编号： | 1001-4861(2005)11-1691-06 |
| 收稿时间： | 3/6/2005 12:00:00 AM |
| 修稿时间： | 2005-06-15 |
Synthesis and Characterization of Nanometer SnO2 by Non-hydrolytic Sol-gel Approach |
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| HE Ze-Qiang,XIONG Li-Zhi,MA Ming-You,XIAO Zhuo-Bing,WU Xian-Ming and HUANG Ke-Long.Synthesis and Characterization of Nanometer SnO2 by Non-hydrolytic Sol-gel Approach[J].Chinese Journal of Inorganic Chemistry,2005,21(11):1691-1696. | |
| Authors: | HE Ze-Qiang XIONG Li-Zhi MA Ming-You XIAO Zhuo-Bing WU Xian-Ming and HUANG Ke-Long |
| Institution: | College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000;College of Chemistry and Chemical Engineering, Central South University, Changsha 410083,College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000,College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000,College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000,College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000 and College of Chemistry and Chemical Engineering, Central South University, Changsha 410083 |
| Abstract: | |
| Keywords: | SnO2 nanometer material sol-gel approach |
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