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TA1[110] phonon dispersion and martensitic phase transition in ordered alloys Fe3Pt
Authors:J Kästner  J Neuhaus  E F Wassermann  W Petry  B Hennion  H Bach
Institution:1. Labor für Tieftemperaturphysik and SFB 166, Gerhard-Mercator-Universit?t Duisburg, 47048, Duisburg, Germany
2. Physik Department E13, Technische Universit?t München, 85747, Garching, Germany
3. Laboratoire Léon Brillouin, CEA Saclay, 91191, Gif-sur-Yvette Cedex, France
4. Institut für Experimentalphysik IV and SFB 166, Ruhr Universit?t Bochum, 44780, Bochum, Germany
Abstract:In a previous neutron scattering study, we had observed that the TA phonon softening in L12-ordered ferromagnetic Fe72Pt28 Invar is pronounced at the zone boundary M-point and leads to an antiferrodistortive phase transition at low temperatures. Here, we report on similar neutron scattering investigations on two ordered crystals with higher Fe content to investigate the relation between the TA phonon softening and the martensitic transformation, which occurs in Fe-rich ordered Fe-Pt. We find that the TA phonon softening, especially at the M-point zone boundary, does not depend on the composition of the investigated crystals. In Fe74.5Pt25.5, however, the antiferrodistortive phase transition temperature is enhanced due to tetragonal strain preceding the martensitic transition. In Fe77Pt23 a precursor driven premartensitic phase transition is not observed. The structure of the martensite is, however, influenced by the soft mode lattice instability of the austenite. This would explain the origin of structural details found previously for Fe3Pt thermoelastic martensite. Received 18 January 1999 and Received in final form 11 March 1999
Keywords:PACS  63  20  Dj Phonon states and bands  normal modes  and phonon dispersion - 81  30  Kf Martensitic transformations - 61  12  -q          Neutron diffraction and scattering
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