Continuous cellulose fiber-reinforced cellulose ester composites III. Commercial matrix and fiber options |
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Authors: | Amara Franko Kevin C Seavey James Gumaer Wolfgang G Glasser |
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Institution: | (1) Biobased Materials Center, Department of Wood Science and Forest Products, Virginia Tech, Blacksburg, VA, 24061 |
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Abstract: | Thermoplastic composites were prepared using two continuous regenerated cellulose fiber types, rayon and lyocell, and with several different commercially-available thermoplastic cellulose esters as matrix. Matrix options included cellulose acetate propionate (CAP), and several cellulose acetate butyrates (CAB) with different butyryl content, having different molecular weights and different methods of plasticization (adipates and very low molecular weight cellulose ester fractions). Choice of cellulose ester type was generally found to have little or no effect on mechanical properties. A significant effect, however, was revealed for fiber type. The lyocell-based composites thereby were reflective of the greater stiffness of a fiber produced from anisotropic solution state. Their modulus consistently exceeded 20GPa whereas the rayon fiber-based composites had moduli between 6 and 8GPa. The latter, however, possessed failure strains that were 3 to 4 times greater than their stiffer counterparts. |
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Keywords: | cellulose esters composites lyocell fibers viscose/rayon |
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