Co(II),
Ni(II) and Cu(II) complexes of 1,4-di-(1-hydroxyimino-2-phenyl-2-oxo-ethylamino)benzene |
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Authors: | M Ta? H Bat? |
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Institution: | 1. Giresun Faculty
of Art and Sciences, Department of Chemistry, Karadeniz
Technical University, Giresun, Turkey, 28049 2. Art-Science Faculty, Department of Chemistry, Ondokuz
Mayis University, Samsun, Turkey, 55139
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Abstract: | The ligand has been
prepared from ω-chloroisonitrosoacetophenone and 1,4-phenylenediamine
in the presence of NaHCO3. The ligand have a C=O group
and an –NH–R group adjacent to the oxime group. The Ni(II), Cu(II)
and Co(II) complexes of the synthesized ligand were prepared and their structures
were identified using FTIR, UV-Vis spectral data, elemental analysis, thermal
analysis and magnetic moment measurements. The metal-ligand ratios were found
to be 3:2. The ligands were found to coordinate to the metal ions via the
oxime nitrogen, oxime oxygen, one of the carbonyl group and amide nitrogen
atoms. Thermal analyses data reveals that the water in the complexes was found
to be non-coordinated to the metal ions. In the trinuclear structures, the
metals have the tetrahedral environments. |
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Keywords: | |
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