Zur Herstellung von 1,2,3-Tricarbonylverbindungen aus 1,3-Dicarbonylverbindungen. 27. Mitteilung über Reduktone und Tricarbonylverbindungen [1] |
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Authors: | Francis Dayer,Huu Lê Dao,Hellmut Gold,Heike Rod -Gowal,Hans Dahn |
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Affiliation: | Francis Dayer,Huu Lê Dao,Hellmut Gold,Heike Rodé-Gowal,Hans Dahn |
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Abstract: | The synthesis of 22 substituted tricarbonyl compounds is reported. They were obtained either by oxidation of β-dicarbonyl compounds with SeO2 or nitrous oxides or by oxidation of the α-bromo-β-dicarbonyl compounds with DMSO. The procedures using SeO2 or DMSO are more rapid and give in general better yields than other methods described in the literature. |
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