Novel metallamacrocyclic gold(I) thiolate cluster complex: structure and luminescence of [Au9(mu-dppm)4(mu-p-tc)6](PF6)3 |
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| Authors: | Chen Jinhua Mohamed Ahmed A Abdou Hanan E Bauer Jeanette A Krause Fackler John P Bruce Alice E Bruce Mitchell R M |
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| Affiliation: | Department of Chemistry, University of Maine, Aubert Hall, Orono, ME 04469-5706, USA. |
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| Abstract: | The structure of a novel metallamacrocyclic phosphine gold(I) thiolate cluster, [Au9(mu-dppm)4(mu-p-tc)6](PF6)3, where dppm = bis(diphenylphosphine)methane and p-tc = p-thiocresolate, is reported and shows AuAu attractions of approximately 3.0 A and gold(I) atoms linked to thiolate and phosphine ligands in distorted trigonal and nearly linear geometries. |
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