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Visible-Light-Induced Photocatalytic C3-Trifluoroethylation of Quinoxalin-2-(1H)-ones
Authors:Jian Liu  Zhibin Huang  Cheng Wang  Zefeng Deng  Xu Xu  Prof Runsheng Zeng  Prof Yingsheng Zhao
Institution:Key Laboratory of Organic Synthesis of Jiangsu Province College of Chemistry Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123 P.R. China
Abstract:A visible-light-induced Rose bengal catalyzed C3-trifluoroethylation of quinoxalin-2-(1H)-ones is reported. A wide range of quinoxalin-2-(1H)-ones was compatible, which led to the corresponding products in moderate to good yields. A gram-scale reaction proceeded well and afforded an efficient route to prepare C3-trifluoroethylated quinoxalin-2-(1H)-ones.
Keywords:trifluoroethylation  photochemistry  synthetic methods  photocatalysis  quinoxalin-2-(1H)-ones
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