| 八面体配合物分子的旋光性和构型 |
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| 引用本文： | 周志华,汤杰,胡秀贞. 八面体配合物分子的旋光性和构型[J]. 无机化学学报, 1989, 5(1): 29-40 |
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| 作者姓名： | 周志华 汤杰 胡秀贞 |
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| 作者单位： | 南京师范大学化学系(周志华，汤杰)，南京师范大学化学系(胡秀贞) |
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| 摘 要： | 在极化度多级圆球不对称模型(该模型运用于含一个或二个不对称碳的有机化合物)和对称性规则的基础上,我们提出了某些规则和八面体配合物的八区律。利用这些规则和规律,八面体配合物的分子构型可以方便的与它们的旋光方向联系起来。
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| 关 键 词： | 旋光性 分子构型 八区律 |
| 收稿时间： | 1987-07-10 |
OPTICAL ACTIVITY AND CONFIGURATION OF MOLECULES OF COORDINATION COMPOUNDS WITH OCTAHEDRAL SHAPE |
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| Zhou Zhihu,Tang jie and Hu Xiuzhen. OPTICAL ACTIVITY AND CONFIGURATION OF MOLECULES OF COORDINATION COMPOUNDS WITH OCTAHEDRAL SHAPE[J]. Chinese Journal of Inorganic Chemistry, 1989, 5(1): 29-40 |
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| Authors: | Zhou Zhihu Tang jie Hu Xiuzhen |
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| Affiliation: | Department of Chemistry, Nanjing Normal University,Department of Chemistry, Nanjing Normal University and Department of Chemistry, Nanjing Normal University |
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| Abstract: | We suggest some regulations and octant rule in coordination compound based on the unsymmetrical model of the multiple spheres of polarizability and symmetry rules.Thc model is suitable for organic compound containing one or two unsymmetrical carbons. By use of these regulations and rules, the molecular configuration of coordination compounds with octahedral shape can be conveniently correlated with their rotatory direction. |
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| Keywords: | optical activity molecular configuration octant rule |
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