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Synthesis and electrochemical studies of LiMn1−xCuXO4 cathode material
Authors:I Ruth Mangani  R Vasanthi  R Chandraskaran  S Selladurai  C Julien
Institution:(1) Solid State Ionics Lab., MIT Campus, Anna University, 600 044 Chennai, India;(2) LMDH, UMR 7603, Université Pierre et Marie Curie, 4 place Jussieu, case 86, 75252 Paris cedex 05, France
Abstract:LiMn1.8Cu0.2O4 was investigated in order to improve the electrochemical properties of LiMn2O4. We report the synthesis and characterization of materials prepared by solid-state reaction. The structural properties evaluated by the X-ray diffraction and vibrational spectroscopy show that a single phase was formed. Conductivity of LiMn1.8Cu0.2O4 cathode is found to be 8×10−6 S/cm at 25 °C. The cyclic voltammetry data shows the reversibility of the electrode material. Paper presented at the 7th Euroconference on Ionics, Calcatoggio, Corsica, France, Oct. 1–7, 2000.
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