The temperature vibrations of urea molecules

The structural and dynamic parameters of urea at 112°K and 295°K were determined by the least squares method. The characteristic temperature of the torsional optical vibrations of a molecule about a C-O bond was determined and is in good agreement with the value determined by Raman scattering. The fractional X-coordinate of the nitrogen atom corrected for torsional vibrations was determined and it was found that the magnitude of the projection of the C-N bond in the given temperature range changes only within the limits of observational errors. A new method, called temperature difference synthesis, is described and it is shown that it is suitable for rapid qualitative determination of the thermal anisotropy of the vibrations of atoms in a crystal lattice.

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112°K 295°K. C-O , , . X- , C-N . , , , .