Organo-iron mediated synthesis of functional dendrimers with 1 → 3 connectivity |
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Authors: | Didier Astruc Jaime Ruiz |
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Affiliation: | Institut des Sciences Moléculaires, UMR CNRS N° 5255, Université Bordeaux 1, 351 Cours de la Libération, 33405 Talence Cedex, France |
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Abstract: | The organo-iron mediated activation of arene in the sandwich complexes [FeCp(η6-arene)][PF6] is shown to produce 1 → 3 connectivity at benzylic positions that was utilized for dendrimer syntheses. This mini-review of the work carried out in the authors’ laboratory summarizes this principle and its applications with emphasis on recent significant improvements in the CpFe+-mediated reactions, recyclability of the CpFe+ group, mechanistic features and examples of efficient and useful functionalization reactions. |
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Keywords: | Organoiron Arene Sandwich complex Dendrimer Olefin |
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