Nickel-catalyzed, base-mediated amination/hydroamination reaction sequence for a modular synthesis of indoles |
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| Authors: | Lutz Ackermann Weifeng Song René Sandmann |
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| Institution: | Institut für Organische und Biomolekulare Chemie, Georg-August-Universitaet, Tammannstrasse 2, 37077 Goettingen, Germany |
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| Abstract: | A catalytic system consisting of Ni(cod)2] and ligand dppf enabled an efficient synthesis of differently substituted indoles through a modular reaction sequence, which consists of intermolecular aminations and intramolecular hydroaminations with ortho-alkynylhaloarenes. |
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| Keywords: | Amination Base Hydroamination Indole Nickel |
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