FeCl3-catalyzed addition of nitrogen and 1,3-dicarbonyl nucleophiles to olefins |
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| Authors: | Christophe Dal Zotto Araceli Zarate-Ruiz David Virieux Vincent Terrasson Anne Gaucher |
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| Institution: | a Institut Charles Gerhardt, UMR 5253 CNRS-UM2-UM1-ENSCM, 8 Rue de l’Ecole Normale, 34296 Montpellier, France
b Institut Lavoisier UMR CNRS 8180, Université de Versailles-Saint-Quentin-en-Yvelines, 45, Avenue des Etats-Unis, F-78035 Versailles, France |
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| Abstract: | A direct intermolecular addition of nitrogen and 1,3-dicarbonyl nucleophiles to stabilized double bonds (styrenes, 1,3-dienes, enol-ethers, sugars.) in the presence of green and inexpensive FeCl3 catalyst is described. |
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| Keywords: | Iron Hydroamination Atom economy |
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