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Application of dimeric cyclopalladated complex of tribenzylamine as an efficient catalyst in the Heck cross-coupling reaction |
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| Authors: | Abdol R. Hajipour Fatemeh Rafiee |
| Affiliation: | a Pharmaceutical Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan 84156, Islamic Republic of Iran b Department of Pharmacology, University of Wisconsin, Medical School, 1300 University Avenue, Madison, WI 53706-1532, USA |
| Abstract: | The activity of [Pd{C6H4(CH2N(CH2Ph)2)} (μ-Br)]2 complex was investigated in the Heck-Mizoroki C-C cross-coupling reaction. This complex is an active and efficient catalyst for the Heck reaction of aryl iodides, bromides and even chlorides and also arenesulfonyl chlorides. The cross-coupled products were produced in excellent yields in short reaction time using a catalytic amount of [Pd{C6H4(CH2N(CH2Ph)2) (μ-Br)]2 complex in NMP at 130 °C. |
| Keywords: | Cyclopalladated complex Catalyst Tribenzylamine Heck reaction |
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