The first example of hydrozirconation of alkynes in room temperature ionic liquids |
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| Authors: | Bin Huang Wenyan Hao |
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| Institution: | a Department of Chemistry, Jiangxi Normal University, Nanchang 330022, PR China
b Department of Chemistry, Jiujiang University, Jiujiang 332000, PR China |
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| Abstract: | Hydrozirconation of terminal alkynes in 1-butyl-3-methylimidazolium hexafluorophosphate (bmim]PF6]) at 30 °C gave highly regio- and stereoselectively (E)-vinylzirconium complexes, which underwent a cross-coupling reaction with aryl halides in the presence of Pd(PPh3)4 to afford (E)-1,2-disubstituted ethenes in good to high yields. Our system not only avoids the use of easily volatile THF or CH2Cl2 as solvent but also solves the basic problem of palladium catalyst reuse. |
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| Keywords: | Hydrozirconation Ionic liquid Palladium catalysis Cross-coupling reaction Green synthesis |
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