The influence of N-heterocyclic carbene steric and electronic properties in Ru-catalysed cross metathesis reactions |
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| Authors: | Cristina Luján |
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| Institution: | EaStCHEM School of Chemistry, University of St Andrews, North Haugh, KY16 9ST, St Andrews, United Kingdom |
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| Abstract: | The present study examines the influence of N-heterocyclic carbene (NHC) ligand electronic and steric parameters on the activity of ruthenium indenylidene complexes in cross metathesis. The NHC ligands tested lead to varied E/Z selectivities with the pre-catalyst bearing an IMes ligand exhibiting high activity. |
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| Keywords: | Olefin metathesis Cross metathesis Ruthenium N-Heterocyclic carbene E/Z isomers |
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