|
|||||
|
|
Nucleophilic properties of Ru(CCH)(dppe)Cp∗: Synthesis and structure of Ru{c-CCArC(O)C(O)O}(dppe)Cp∗ [Ar = 2,4-(NO2)2C6H3] |
|
| Authors: | Michael I Bruce Jonathan C Morris Brian W Skelton |
| Institution: | a School of Chemistry & Physics, University of Adelaide, Adelaide, South Australia 5005, Australia b School of Chemistry, University of New South Wales, Sydney, NSW 2052, Australia c Centre for Microscopy, Characterisation and Analysis, University of Western Australia, Crawley, Western Australia 6009, Australia |
| Abstract: | The complex Ru{c-C CArC(O)C(O)O}(dppe)Cp∗ Ar = 2,4-(NO2)2C6H3] 2, containing a dihydrofuran-3,4-dione ligand, was obtained from a reaction between the strong nucleophile Ru(C CH)(dppe)Cp∗ 1 and bis(2,4-dinitrophenyl) oxalate. The X-ray determined molecular structure of 2 is reported, together with a plausible route for its formation. |
| Keywords: | Ruthenium Metalla-alkynyl ketone Cyclisation Dihydrofuran X-ray structure |
| 本文献已被 ScienceDirect 等数据库收录！ | |