Synthesis and electrochemical properties of crown ether functionalized coumarin substituted cobalt and copper phthalocyanines |
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Authors: | Aliye Asl? Esenp?nar Mustafa Bulut |
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Institution: | a K?rklareli University, Department of Chemistry, 39100, K?rklareli, Turkey b Marmara University, Faculty of Art and Science, Department of Chemistry, Kadikoy 34722, Istanbul, Turkey |
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Abstract: | The synthesis of novel 6,7-15-crown-5]-3-p-(3,4-dicyanophenoxy)phenyl]coumarin (1)/6,7-15-crown-5]-3-p-(2,3-dicyanophenoxy)phenyl]coumarin (2) and their peripherally/non-peripherally cobalt and copper phthalocyanine complexes (3-6) have been prepared and characterized by elementel analysis, 1H-NMR, MALDI-TOF, FT-IR and UV-Vis spectral data. Fluorescence intensity changes of compound 1 and 2 have been determined by addition of Na+ or K+ ions at 25 °C in THF. The effect of substitution type on the redox and aggregation behaviour of the compounds was investigated by voltammetry and in situ spectroelectrochemistry. |
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Keywords: | Coumarin (2H-chromen-2-one) Crown ether Phthalocyanine Fluorescence Electrochemistry |
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