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Iridium as a general catalyst for the decarbonylative addition of aldehydes to alkynes |
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| Authors: | Jun Wang Xiangyu Guo |
| Institution: | a Department of Chemistry, McGill University, 801 Sherbrooke Street West, Montreal, QC, Canada H3A 2K6 b Department of Polypropylene, Beijing Research Institute of Chemical Industry, SINOPEC, Beijing 100013, PR China |
| Abstract: | A general catalytic system for the decarbonylative addition reaction of aldehydes with alkynes is developed by using an iridium catalyst system. Both aromatic and aliphatic aldehydes reacted with terminal alkynes efficiently to give the corresponding olefination products in high yields and up to 11:1 E/Z selectivity. |
| Keywords: | Decarbonylation Coupling Aldehyde Alkyne Iridium |
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