Branch selective allylation of acetylacetone catalyzed by Water-soluble rhodium complex catalyst |
| |
Authors: | Nobuyuki Komine |
| |
Institution: | Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, 2-24-16 Nakacho, Koganei, Tokyo 184-8588, Japan |
| |
Abstract: | RhCl(1,5-cod)]2/PTA is highly active branch-selective catalyst for C-allylation of acetylacetone by allylic carbonates in water/ethyl acetate biphasic system, where either crotyl or 1-methylallyl carbonates gives sterically congested branched allylation product, suggesting formation of a common allylrhodium intermediate. |
| |
Keywords: | Water-soluble rhodium complex Branch-selective allylation Biphasic Catalysis |
本文献已被 ScienceDirect 等数据库收录! |
|