Synthesis and structure of new Schiff base derivatives obtained from 2-(formylphenyl)mercury bromide |
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| Authors: | Rajesh S. Baligar Harkesh B. Singh Ray J. Butcher |
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| Affiliation: | a Department of Chemistry, Indian Institute of Technology Bombay, Powai 400076, Mumbai, India
b Department of Chemistry, Howard University, Washington, DC 20059, USA |
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| Abstract: | Reactions of (2-formylphenyl)mercury(II) bromide 10 with primary amines give mono-, bis- and tris- Schiff base derivatives (11-18). Structures of the synthesized compounds show the presence of five-membered intramolecular Hg?N interaction. Luminescence studies of the compounds have been performed. Attempts to use the synthesized compounds for binding neutral donor molecules or fluoride ions were unsuccessful. |
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| Keywords: | Organomercury Mercuration Metallamacrocycle Intramolecular interaction Anion binding |
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