A SIMPLE ACCESS TO UNSOLVATED MONOMERIC COMPLEXES OF EARLY LANTHANIDE IODIDES(CH_3OCH_2CH_2C_5H_4)_2LnI(Ln=La,Nd)VIA THE REACTION OF[(CH_3OCH_2CH_2C_5H_4)_2LnCl]_2 WITH NaI AND X-RAY CRYSTAL STRUCTURE OF THE LANTHANUM COMPLEX 期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

A SIMPLE ACCESS TO UNSOLVATED MONOMERIC COMPLEXES OF EARLY LANTHANIDE IODIDES(CH_3OCH_2CH_2C_5H_4)_2LnI(Ln=La,Nd)VIA THE REACTION OF[(CH_3OCH_2CH_2C_5H_4)_2LnCl]_2 WITH NaI AND X-RAY CRYSTAL STRUCTURE OF THE LANTHANUM COMPLEX

摘要：	(CH_3OCH_2CH_2C_5H_4)_2LnI(Ln=La,Nd)complexes have beensynthesized by the reaction between NaI and[(CH_3OCH_2CH_2C_5H_4)_2LnCl]2in THF;A single crystal X-ray study has shown that the lanthanumcomplex is an unsolvated monomer with lanthanum(Ⅲ)in a trigonalbipyramidal coordination geometry if the cyclopentadienyl ring isregarded as occupying a single polyhedral vertex.
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