Reactions of mercury salts with benzo- and tetrafluorobenzobarrelenes |
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| Authors: | Sokolova T N Grishin Yu K Timofeev I V Kartashov V R |
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| Institution: | (1) Nizhnii Novgorod Technical State University, 24 ul. Minina, 603600 Nizhnii Novgorod, Russian Federation;(2) Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899 Moscow, Russian Federation |
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| Abstract: | Regiochemistry and stereochemistry of the addition of mercury salts to benzobarrelene and tetrafluorobenzobarrelene have been studied in acetic acid and methanol. The effect of the substrate structure on the regiochemistry of the reaction is discussed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1105–1108, June, 1994. |
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| Keywords: | benzobarrelenes solvo- and azidomercuration regiochemistry regioisomers structure Hg-double bond coordination effect on the ratio of isomeric products |
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