| Er3+单掺和Er3+/Yb3+双掺铋硼酸盐玻璃的研究 |
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| 引用本文： | 吴昌根,夏海平,章践立,王金浩,姚连增. Er3+单掺和Er3+/Yb3+双掺铋硼酸盐玻璃的研究[J]. 光学学报, 2004, 24(5): 78-682 |
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| 作者姓名： | 吴昌根 夏海平 章践立 王金浩 姚连增 |
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| 作者单位： | 1. 中国科学技术大学材料科学与工程系,合肥,230026
2. 宁波大学光电子材料研究所,宁波,315211 |
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| 基金项目： | 浙江省自然科学基金 (5 0 2 16 4 )，宁波市光电子功能材料重点实验室 (994 10 0 2 )资助课题 |
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| 摘 要： | 用高温熔融法制备了Er^3 单掺和Er^3 /Yb^3 双掺铋硼酸盐玻璃样品，测量了上述玻璃样品的吸收光谱，荧光光谱，荧光寿命以及红外透过率。对高浓度掺杂Er^3 的铋硼酸盐玻璃中的浓度猝灭现象作出了解释。分析了Er^3 ／Yb^3 双掺铋硼酸盐玻璃样品中Yb^3 离子对Er^3 离子的敏化过程。研究发现Er^3 ／Yb^3 双掺铋硼酸盐玻璃在1．5～1．6μm波段有宽达81nm的荧光半峰全宽。实验还发现在熔制过程中通入氧气对其荧光寿命和红外透过率都有明显的提高。由于该玻璃材料表现出较好的物化性能。因此该材料可望成为宽带光纤放大器的适宜的基质材料。
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| 关 键 词： | 铒离子单掺杂 光学材料 铒离子／镱离子双掺杂 荧光光谱 铋硼酸盐玻璃 宽带 |
| 收稿时间： | 2003-03-17 |
Study on Er3+-Doped and Er3+/Yb3+ Co-Doped Bismuth Borate Glasses |
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| Wu Changgen Xia Haiping Zhang Jianli Wang Jinghao Yao Lianzeng Materials Science , Engineering Department,University of Science , Technology of China,Hefei Laboratory of Photo-Electronic Materials,Ningbo University,Ningbo. Study on Er3+-Doped and Er3+/Yb3+ Co-Doped Bismuth Borate Glasses[J]. Acta Optica Sinica, 2004, 24(5): 78-682 |
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| Authors: | Wu Changgen Xia Haiping Zhang Jianli Wang Jinghao Yao Lianzeng Materials Science & Engineering Department University of Science & Technology of China Hefei Laboratory of Photo-Electronic Materials Ningbo University Ningbo |
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| Affiliation: | Wu Changgen 1 Xia Haiping 2 Zhang Jianli 2 Wang Jinghao 2 Yao Lianzeng 1 1 Materials Science & Engineering Department,University of Science & Technology of China,Hefei 230026 2 Laboratory of Photo-Electronic Materials,Ningbo University,Ningbo 315211 |
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| Abstract: | Some bismuth borate glasses with Er3+-doped and Er3+/Yb3+ co-doped are fabricated by the technique of high-temperature melting. The absorption and fluorescence spectra, fluorescence lifetime and transmission in infrared range are measured. Explanation of concentration quenching in case of high level Er3+-doped the bismuth borate glasses is given. The sensitizing of Yb3+ to Er3+ in Er3+/Yb3+ co-doped bismuth borate glasses is discussed. It is found that the band around 1.5～1.6 μm in Er3+/Yb3+ co-doped bismuth borate glass reaches 81 nm and the fluorescence lifetime of Er3+ is enhanced obviously when the glass is treated with oxygen in melting process. In the meantime the glasses show favorable chemical and physical properties. It is expected to be a favorable candidate host for broadband amplifiers. |
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| Keywords: | optical material bismuth borate glass Er 3+ /Yb 3+ co-doping fluorescence spectra broadband |
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