| SYNTHESIS OF POLYBUTADIENE MACROINITIATOR AND POLYBUTADIENE/POLYACRYLAMIDE BLOCK COPOLYMERS |
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| 引用本文： | 方天如,王家行,方政,刘沛妍. SYNTHESIS OF POLYBUTADIENE MACROINITIATOR AND POLYBUTADIENE/POLYACRYLAMIDE BLOCK COPOLYMERS[J]. 高分子科学, 1995, 0(3): 244-251 |
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| 作者姓名： | 方天如 王家行 方政 刘沛妍 |
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| 作者单位： | Changchun Institute of Applied Chemistry，Academia Sinica，Changchun 130022，Changchun Institute of Applied Chemistry，Academia Sinica，Changchun 130022，Changchun Institute of Applied Chemistry，Academia Sinica，Changchun 130022，Department of Chemistry，The Northeast Normal University，Changchun 130024 |
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| 基金项目： | This work was supported by the National Natural Science Foundation of China(Grant 2907200) |
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| 摘 要： | An azo-group containing polybutadiene macroinitiator was prepared by Pinner synthesisand characterized by IR, NMR, GPC, viscosity and elemental measurements. Themacroinitiator was further used to polymerize acrylamide (AAm) in benzene to formpolybutadiene/polyacrylamide (PBD/PAAm) block copolymers. High conversion of AAm wasobtained over a wide range of monomer/macroinitiator ratios. The PBD/PAAm blockcopolymers.were found to have excellent solvent resistance.
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| 收稿时间： | 1994-02-26 |
SYNTHESIS OF POLYBUTADIENE MACROINITIATOR AND POLYBUTADIENE/POLYACRYLAMIDE BLOCK COPOLYMERS* |
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| FANG Tianru,WANG Jiahang,FANG Zheng,LIU Peiyan. SYNTHESIS OF POLYBUTADIENE MACROINITIATOR AND POLYBUTADIENE/POLYACRYLAMIDE BLOCK COPOLYMERS*[J]. Chinese Journal of Polymer Science, 1995, 0(3): 244-251 |
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| Authors: | FANG Tianru WANG Jiahang FANG Zheng LIU Peiyan |
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| Affiliation: | Changchun Institute of Applied Chemistry; Academia Sinica; Changchun 130022 Department of Chemistry; The Northeast Normal University; Changchun 130024 |
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| Abstract: | An azo-group containing polybutadiene macroinitiator was prepared by Pinner synthesisand characterized by IR, NMR, GPC, viscosity and elemental measurements. Themacroinitiator was further used to polymerize acrylamide (AAm) in benzene to formpolybutadiene/polyacrylamide (PBD/PAAm) block copolymers. High conversion of AAm wasobtained over a wide range of monomer/macroinitiator ratios. The PBD/PAAm blockcopolymers.were found to have excellent solvent resistance. |
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| Keywords: | Azo-containing polybutadiene macroinitiator PBD/PAAm block copolymer Amphiphilic polymer |
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