| NaA Zeolite Membrane with High Performance Synthesized by Vapor Phase Transformation Method |
| |
| 引用本文： | 程志林,晁自胜,林海强,万惠霖. NaA Zeolite Membrane with High Performance Synthesized by Vapor Phase Transformation Method[J]. 中国化学, 2003, 21(11): 1430-1432. DOI: 10.1002/cjoc.20030211107 |
| |
| 作者姓名： | 程志林 晁自胜 林海强 万惠霖 |
| |
| 作者单位： | Department of Chemistry，East China Normal University，Department of Chemistry，State Key Laboratory for Physical Chemistry of Solid Surface，Xiamen University，Department of Chemistry，State Key Laboratory for Physical Chemistry of Solid Surface，Xiamen University，Department of Chemistry，State Key Laboratory for Physical Chemistry of Solid Surface，Xiamen University Shanghai 200062，China，Department of Chemistry，State Key Laboratory for Physical Chemistry of Solid Surface，Xiamen University，Xiamen，Fujian 361005，China，Xiamen，Fujian 361005，China，Xiamen，Fujian 361005，China，Xiamen，Fujian 361005，China |
| |
| 基金项目： | ProjectsupportedbyMinistryofScienceandTechnologyofChina (No .G19990 2 2 40 8)andtheNationalNaturalScienceFoundationofChina (No .K16161) |
| |
| 摘 要： | IntroductionZeolitemembranes ,asaremarkablebranchofinor ganicmembrane ,havepotentialadvantagesinmanyappli cationssuchascatalysisandseparation ,chemicalsensors ,ascousticwavedevices ,andmicroelectronicdevicesduetotheiruniformporesizeatthemolecularlevelandresis tancetohightemperature .1 5For 10years ,manyre searchershavepaidconsiderableattentiontosynthesisofzeolitemembraneswithhighperformance .Amongthere portedzeolitemembranes ,mostattentionwasfocusedonsynthesisofMFI typezeolitemembranebecausei…
|
| 关 键 词： | NaA沸石膜 性能 合成 汽相转换 分离 |
NaA Zeolite Membrane with High Performance Synthesized by Vapor Phase Transformation Method |
| |
| CHENG,Zhi-Lin,a,b CHAO,Zi-Sheng b LIN,Hai-Qiang b WAN,Hui-Lin b a. NaA Zeolite Membrane with High Performance Synthesized by Vapor Phase Transformation Method[J]. Chinese Journal of Chemistry, 2003, 21(11): 1430-1432. DOI: 10.1002/cjoc.20030211107 |
| |
| Authors: | CHENG Zhi-Lin a b CHAO Zi-Sheng b LIN Hai-Qiang b WAN Hui-Lin b a |
| |
| Affiliation: | CHENG,Zhi-Lin,a,b CHAO,Zi-Sheng b LIN,Hai-Qiang b WAN,Hui-Lin b aDepartment of Chemistry,East China Normal University,Shanghai 200062,China bDepartment of Chemistry,State Key Laboratory for Physical Chemistry of Solid Surface,Xiamen University,Xiamen,Fujian 361005,China |
| |
| Abstract: | NaA zeolite membrane was synthesized with high permeance on porous alumina substrate by the vapor phase transformation method. The membranes were characterized by XRD and SEM techniques. The XRD results showed that the membranes after the synthesis time of 24 h consisted of the pure NaA zeolite crystals. The SEM results showed that the membranes after the synthesis time of 48 h consisted of intergrown zeolite crystals. The H2 permeance of the NaA zeolite membranes was higher than 2.0 × 10?6 mol/(Pa · m2 · s), and the maximum of the gas H2/C3H8 permselectivity was 7.15, which is higher than the corresponding Knudsen diffusion selectivity of which is 4.69. |
| |
| Keywords: | NaA zeoltie membrane vapor phase transformation synthesis separation |
| 本文献已被 CNKI 等数据库收录！ |
|
