| 一维链状铜配位聚合物[Cu(bpb)0.5(CH3COO)2]n的合成与晶体结构 |
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| 引用本文： | 朱莉娜,高山,霍丽华.一维链状铜配位聚合物[Cu(bpb)0.5(CH3COO)2]n的合成与晶体结构[J].无机化学学报,2008,24(4):670-672. |
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| 作者姓名： | 朱莉娜 高山 霍丽华 |
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| 作者单位： | 黑龙江大学化学化工与材料学院功能材料室,哈尔滨,150080 |
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| 基金项目： | 黑龙江省自然科学基金
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黑龙江省高校骨干教师资助项目 |
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| 摘 要： | A coordination complex of Cu(bpb)0.5(CH3COO)2]n (bpb=1,4-bis(pyridine-3-aminomethyl)benzene) has been synthesized and characterized by elemental analysis, IR spectra, TG and X-ray single crystal diffraction. The title complex crystallizes in triclinic with space group P1, a=0.771 98(15) nm, b=0.827 62(17) nm, c=1.116 0(2) nm, α=96.71(3)°, β=90.03(3)°, γ=105.39(3)°, and V=0.682 4(3) nm3, Z=2, R=0.042 4, wR=0.091 1. The title complex is composed of dicopper tetracarboxylate units. Copper(Ⅱ) atom asumes a square-pyramidal coordination geometry formed with one pyridyl N atom from bpb and four O atoms from four bridging acetate anions. Two adjacent dicopper tetracarboxylate units are linked into a 1D chain by the bpb ligands, which were further connected by inter-chain hydrogen bonds to form a 2D network structure. CCDC: 667605.
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| 关 键 词： | 铜配位聚合物 合成 晶体结构 |
| 文章编号： | 1001-4861(2008)04-0670-03 |
| 修稿时间： | 2007年11月19 |
Synthesis and Crystal Structure of 1D Copper Coordination Polymer [Cu(bpb)0.5(CH3COO)2]n |
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| ZHU Li-N,GAO Shan and HUO Li-Hua.Synthesis and Crystal Structure of 1D Copper Coordination Polymer [Cu(bpb)0.5(CH3COO)2]n[J].Chinese Journal of Inorganic Chemistry,2008,24(4):670-672. |
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| Authors: | ZHU Li-N GAO Shan and HUO Li-Hua |
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| Institution: | Laboratory of Functional Materials, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080,Laboratory of Functional Materials, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080 and Laboratory of Functional Materials, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080 |
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| Abstract: | |
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| Keywords: | copper coordination polymer synthesis crystal structure |
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