Catalytic thia-Sommelet-Hauser rearrangement: application to the synthesis of oxindoles |
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| Authors: | Li Yuye Shi Yi Huang Zhongxing Wu Xinhu Xu Pengfei Wang Jianbo Zhang Yan |
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| Institution: | Beijing National Laboratory of Molecular Sciences (BNLMS), College of Chemistry, Peking University, Beijing, China. |
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| Abstract: | A series of 3-arylthio-1,3-disubstituted-oxindoles were prepared in good yields by the reaction of α-diazocarbonyl compounds and sulfenamides. The reaction involves a Rh-catalyzed thia-Sommelet-Hauser-type rearrangement. |
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