Reductive cyclization cascades of lactones using SmI2-H2O |
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Authors: | Parmar Dixit Price Kieran Spain Malcolm Matsubara Hiroshi Bradley Paul A Procter David J |
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Institution: | School of Chemistry, University of Manchester, Manchester, United Kingdom. |
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Abstract: | Lactones bearing two alkenes or an alkene and an alkyne undergo reductive cyclization cascades upon treatment with SmI(2)-H(2)O, giving decorated azulene motifs in excellent yields with good diastereocontrol. |
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