Pd-NHC catalyzed conjugate addition versus the Mizoroki-Heck reaction |
| |
| Authors: | Gottumukkala Aditya L de Vries Johannes G Minnaard Adriaan J |
| |
| Affiliation: | Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, The Netherlands. |
| |
| Abstract: | Ace of base: A catalytic system is presented that, solely by choice of the base, selectively switches between conjugate addition and the Mizoroki-Heck reaction of aryl halides with Michael acceptors (see scheme; R, R' = alkyl, aryl). For conjugate addition reactions, this avoids the preparation and use of organometallics. |
| |
| Keywords: | base conjugate addition carbenes. elimination palladium |
| 本文献已被 PubMed 等数据库收录！ |
|
