Biaryl synthesis from two different aryl halides with tri(2-furyl)germane |
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| Authors: | Nakamura Tomoaki Kinoshita Hidenori Shinokubo Hiroshi Oshima Koichiro |
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| Affiliation: | Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Japan. |
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| Abstract: | [reaction: see text] The coupling reaction of germanium compounds with aryl halides has been developed. The Pd(0)-catalyzed reaction of aryl halides with tri(2-furyl)germane provides aryltri(2-furyl)germanes in good yield. The cross-coupling reaction of aryltri(2-furyl)germanes with aryl halides is achieved. This allows facile synthesis of unsymmetrical biaryls from two different aryl halides. |
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