Coordination chemistry umpolung: a gallane ligand on a phosphine lewis acceptor. |
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| Authors: | Neil Burford Paul J Ragogna Katherine N Robertson T Stanley Cameron Ned J Hardman Philip P Power |
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| Institution: | Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, Canada. |
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| Abstract: | Pentaphenylphosphinophosphonium trifluoromethanesulfonate reacts with amino-iminogall(I)ane to effect quantitative substitution of Ph3P and formation of the first complex of a gallium Lewis base on a phosphine Lewis acid. |
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