Spin relaxation studies of the muonium substituted ethyl radical in the gas phase |
| |
| Authors: | D G Fleming R F Kiefl D M Garner M Senba A C Gonzalez J R Kempton D J Arsenau K Venkateswaran P W Percival J -C Brodovitch S -K Leung D Yu S F J Cox |
| |
| Institution: | (1) TRIUMF and Department of Chemistry, UBC, Vancouver, BC, Canada;(2) TRIUMF and Department of Physics and Chemistry, UBC, Vancouver, Canada;(3) TRIUMF and Department of Chemistry, Simon Fraser University, Burnaby, BC, Canada;(4) Rutherford Appleton Laboratory, Chilton, Oxfordshire, U.K. |
| |
| Abstract: | This short communication draws attention to the power of μSR and related measurements in providing an unusually complete characterisation
of muonium substituted organic radicals in the gas phase. Spectroscopic information is available from muon spin rotation and
muon level crossing resonance, giving all the nuclear hyperfine coupling constants, just as in the liquid phase. In addition,
measurements of the relaxation time of the muon Zeeman energy become possible; these are potentially informative on the molecular
collision dynamics. Demonstration results are presented in summary for the muonium substituted ethyl radical, ĊH2CH2Mu, in ethene gas. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
