Molecular structures of thimerosal (Merthiolate) and other arylthiolate mercury alkyl compounds |
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| Authors: | Melnick Jonathan G Yurkerwich Kevin Buccella Daniela Sattler Wesley Parkin Gerard |
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| Affiliation: | Department of Chemistry, Columbia University, New York, New York 10027, USA. |
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| Abstract: | The molecular structure of sodium ethylmercury thiosalicylate (also known as thimerosal and Merthiolate) and related arylthiolate mercury alkyl compounds, namely PhSHgMe and PhSHgEt, have been determined by single crystal X-ray diffraction. (1)H NMR spectroscopic studies indicate that the appearance of the (199)Hg mercury satellites of the ethyl group of thimerosal is highly dependent on the magnetic field and the viscosity of the solvent as a consequence of relaxation due to chemical shift anisotropy. |
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