Gas-phase generation of highly reactive hexatriyne-bridged [6n]paracyclophynes |
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| Authors: | Umeda Rui Morinaka Takayoshi Sonoda Motohiro Tobe Yoshito |
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| Institution: | Division of Frontier Materials Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka 560-8531, Japan. |
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| Abstract: | 6n]Paracyclophenediynes 2a-d (n = 3-6) having 4.3.2]propellatriene units were prepared as precursors of the corresponding 6n]paracyclophynes. Laser irradiation of 2a-d produced the negative ions of 6n]paracyclophynes 1a-d (n = 3-6) by extrusion of the indan fragments, which were detected by time-of-flight mass spectrometry. |
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