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Complex Formation by Galacturonic Acid with Copper(II) and Neodymium(III) Ions in Water Solution
Authors:Shestavin  A I  Bolotin  S N  Bukov  N N  Panyushkin  V T
Institution:(1) Kuban State University, Krasnodar, Russia
Abstract:Complex formation by galacturonic acid with copper(II) ion in water solution is studied by themethods of EPR spectroscopy. At the pH > 3 the EPR signal (g 2.174) confirms the complex formation at theligand carboxylic group. The following complex formation parameters are measured: equilibrium constant'g factor, hyperfine coupling constant, average complex lifetime. From the data of electron spectra invisible region the complex composition and stability constant is defined for copper(II) and neodymium(III).
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