Theory,preparation, properties and catalysis application in 2D graphynes-based materials |
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Authors: | Ning Zhang Jiayu Wu Taoyuan Yu Jiaqi Lv He Liu Xiping Xu |
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Institution: | College of Photoelectrical Engineering, Changchun University of Science and Technology, Changchun 130022, China |
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Abstract: | Carbon has three hybridization forms of sp?, sp2? and sp3?, and the combination of different forms can obtain different kinds of carbon allotropes, such as diamond, carbon nanotubes, fullerene, graphynes (GYs) and graphdiyne (GDY). Among them, the GDY molecule is a single-layer two-dimensional (2D) planar structure material with highly π-conjugation formed by sp? and sp2? hybridization. GDY has a carbon atom ring composed of benzene ring and acetylene, which makes GDY have a uniformly distributed pore structure. In addition, GDY planar material have some slight wrinkles, which makes GDY have better self-stability than other 2D planar materials. The excellent properties of GDY make it attract the attention of researchers. Therefore, GDY is widely used in chemical catalysis, electronics, communications, clean energy and composite materials. This paper summarizes the recent progress of GDY research, including structure, preparation, properties and application of GDY in the field of catalysts. |
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Keywords: | 2D materials catalysis application graphyne property |
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