Facile and new convenient route for synthesis of some C2-symmetric bidentate phosphine ligands derived from d-mannitol |
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Affiliation: | Department of Chemistry, Faculty of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia |
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Abstract: | The preparation of two novel C2 symmetric bidentate phosphine ligands derived from cheap and available D-mannitol has been reported. These new ligands accompanied by unprecedented one-pot reaction for the regioselective reductive opening of 1,3:4,6-di-O-benzylidene-D-mannitol have been achieved. All reported compounds are fully characterized by standard analytical methods including the measurement of optical activities. |
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Keywords: | Phosphine ligands Carbohydrates Homogeneous catalysis Chiral auxiliaries |
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