Self-promoted electron transfer from cobalt(II) porphyrin to p-fluoranil to produce a dimer radical anion-cobalt(III) porphyrin complex |
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| Authors: | Okamoto Ken Fukuzumi Shunichi |
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| Institution: | Department of Material and Life Science, Graduate School of Engineering, Osaka University, CREST, Japan Science and Technology Corporation (JST), Suita, Osaka 565-0871, Japan. |
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| Abstract: | Self-promoted electron transfer from a cobalt(II) porphyrin Co(II)OEP] to p-fluoranil (F4Q) occurs, exhibiting a second-order dependence of the electron-transfer rate with respect to the F4Q concentration due to the formation of a strong complex between the dimer radical anion (F4Q)2*-] and the resulting Co(III)OEP+. |
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