| 从范德华力理论看Grunwald-Winstein方程中的Y因子 |
| |
| 引用本文： | 王风云,陈民生. 从范德华力理论看Grunwald-Winstein方程中的Y因子[J]. 南京理工大学学报(自然科学版), 1988, 0(4) |
| |
| 作者姓名： | 王风云 陈民生 |
| |
| 作者单位： | 华东工学院化学工程系(王风云)，华东工学院化学工程系(陈民生) |
| |
| 摘 要： | 应用范德华力理论,导出了动力学介质效应公式.以叔丁基氯在水—乙醇、水—甲醇、水—二氧六环和水—丙酮体系中的溶剂解反应为研究对象,分析、讨论了Grunwald-Winstein方程中Y因子的具体内容,理论计算的Y值与文献值具有较好的一致性.
|
| 关 键 词： | 范德华力[31JA 32FC] 方程[30A] 因子[30B] |
A Discussion of Y Factor in Grunwald-Winstein Equation According to Van Der Waals Theory |
| |
| Wang Fengyun,Chen Minsheng. A Discussion of Y Factor in Grunwald-Winstein Equation According to Van Der Waals Theory[J]. Journal of Nanjing University of Science and Technology(Nature Science), 1988, 0(4) |
| |
| Authors: | Wang Fengyun Chen Minsheng |
| |
| Affiliation: | Wang Fengyun;Chen Minsheng |
| |
| Abstract: | This paper is a theoretical analysis for theY factor in Grunwald-Winstein equation by the van der waals'theory,taking the solvolysis reaction of t-BuClin the mixturesof EtOH-H_2O, Me OH-H_2O, 1, 4-Dioxane-H_2O and Me_2CO-H_2Oas the example. The factor Y in Grunwald-Winstein equation isdiscussed. It is shown that the theoretically calculated velueof Y is more consistent with that in literature. |
| |
| Keywords: | Van Der waals' Forces Equations Factor |
| 本文献已被 CNKI 等数据库收录！ |
