Hammett acidity function of water-salt solutions of strong acids |
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Authors: | S G Sysoeva I S Kislina M I Vinnik |
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Institution: | (1) N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow |
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Abstract: | The values of the acidity function H0
s of HCl-KCl-H2O solutions (mKCl=2.73, 3.61) at 25°C were determined by the indicator method. An infinitely dilute solution of the acid in a H2O-KCl mixture of fixed composition is the standard state for H0
s. A method for calculation of H0
s of water-salt solutions of strong mineral acids was proposed.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2434–2437, November, 1989. |
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