| 手性酰胺聚硅氧烷固定相的制备与气相色谱性能 |
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| 引用本文： | 周喜春,张立峰,吴采樱,卢雪然,陈远荫. 手性酰胺聚硅氧烷固定相的制备与气相色谱性能[J]. 分析化学, 1995, 0(9) |
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| 作者姓名： | 周喜春 张立峰 吴采樱 卢雪然 陈远荫 |
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| 作者单位： | 武汉大学化学系!武汉430072武汉大学环境科学系(周喜春)，武汉大学化学系!武汉430072(张立峰，吴采樱，卢雪然，陈远荫) |
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| 摘 要： | 以L-苯丙氨酸,L-缬氨酸为手性源,合成了二种含末端烯基,具有刚性苯基链节的新型手性酰胺单体;并通过硅氢加成方法将其接枝到含氢硅油上,制备了两种新型手性酰胺聚硅氧烷固定相.这一新方法具有简单易行,各步产率较高的优点,所制备的手性固定相具有较好的毛细管柱色谱性能.手性拆分能力和耐温性.
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| 关 键 词： | 手性固定相 气相色谱 对映体分离 聚硅氧烷 硅氢加成 |
Preparation of Chiral Amide-type Polysiloxane Stationary Phases and Its Gas Chromatographic Property |
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| Zhou Xichun,Zhang Lifeng,Wu Caiying,Lu Xueran,Chen Yuanyin. Preparation of Chiral Amide-type Polysiloxane Stationary Phases and Its Gas Chromatographic Property[J]. Chinese Journal of Analytical Chemistry, 1995, 0(9) |
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| Authors: | Zhou Xichun Zhang Lifeng Wu Caiying Lu Xueran Chen Yuanyin |
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| Abstract: | Two amide-type chiral moieties containing end-alkenes and rigid unit of phenyl group were synthesized using L-phenylalanine and L-valine as chiral sources, and two novel chiral polysiloxanes were prepared by hydrosilylating these moieties onto polyhy-dromethylsiloxanes. This method was found to be extensively applicable to make chiral amidepolysiloxane phase; and it provides some advantages: they are straightforward and have high yield for each synthetic pathway. The prepared chiral phases own good chro-matographic property and effective enantiomer separation ability as well as good thermosta-bility. |
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| Keywords: | Chiral stationary phase gas chromatography enantiomer separation polysilox-ane hydrosilylation |
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