| Heteropolymolybdate as a New Reaction-controlled Phase-transfer Catalyst for Efficient Alcohol Oxidation with Hydrogen Peroxide |
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| 引用本文： | Zhi Huan WENG Jin Yan WANG Xi Gao JIAN. Heteropolymolybdate as a New Reaction-controlled Phase-transfer Catalyst for Efficient Alcohol Oxidation with Hydrogen Peroxide[J]. 中国化学快报, 2006, 17(6): 848-850 |
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| 作者姓名： | Zhi Huan WENG Jin Yan WANG Xi Gao JIAN |
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| 作者单位： | Zhi Huan WENG，Jin Yan WANG，Xi Gao JIAN Department of Polymer Science and Materials，Dalian University of Technology，Liaoning High Performance Polymer Engineering Research Center，Dalian 116012 |
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| 摘 要： | Aldehydes are very important raw materials or intermediates, which have widespread applications in the perfumery, pharmaceutical, dyestuff and agrochemical industries1. Oxidation of alcohol is one of the most frequently used synthetic reactions in the lab…
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| 关 键 词： | 杂聚钼酸盐 反应-控制相转移催化剂 乙醇 氧化作用 过氧化氢 |
| 收稿时间： | 2005-12-07 |
Heteropolymolybdate as a New Reaction-controlled Phase-transfer Catalyst for Efficient Alcohol Oxidation with Hydrogen Peroxide |
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| Zhi Huan WENG,Jin Yan WANG,Xi Gao JIAN. Heteropolymolybdate as a New Reaction-controlled Phase-transfer Catalyst for Efficient Alcohol Oxidation with Hydrogen Peroxide[J]. Chinese Chemical Letters, 2006, 17(6): 848-850 |
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| Authors: | Zhi Huan WENG Jin Yan WANG Xi Gao JIAN |
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| Abstract: | A new catalytic process for the synthesis of aldehyde from alcohol by oxidation with H2O2 with high selectivity was studied. In this system, heteropolymolybdate [C7H7N(CH3)3]3 {PO4[MoO(O2)2]4} was utilized as the reaction-controlled phase-transfer catalyst to catalyze oxidation of benzyl and aliphatic alcohols. The molar ratio of H2O2 and alcohol was 0.75, no other by-products were detected by gas chromatography, the results of oxidation reaction indicated that the catalyst has high activity and stability. |
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| Keywords: | Heteropolymolybdate reaction-controlled phase-transfer alcohol oxidation. |
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